Toon/Cel Shading (Pokémon X/Y Style?)

[alexmach1]

The first screenshot of blender IS my material settings! all i did is make a brand new material, and set it to shadeless
if u still need more help, just say so and i'll post screenshots of the material and texture settings

should have clarified that I was asking sketchasaurus.

is this the desired effect that you want? I used the brawl charizard model as a base.